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シリカ(SiO2)およびシリコン(Si)関連材料

アモルファスシリカ微粒子透明焼結体(7 nm, fumed silica calcinated at 980oC for 168h)


Emission quantum yield: ca 1%
PL: 500 nm
PLE: below 280 nm
Fast component:Single exponential decay
Slow component: Stretched exponential decay
Ref: T. Uchino and T. Yamada, APL 85, 1164 (2004); T. Yamada and T. Uchino, APL 87, 081904 (2005)

アモルファスシリカ微粒子(7 nm, fumed silica calcinated at 300oC for 2h)


Emission quantum yield: 2-3 %
PL: 435 nm
PLE: 250 and 350 nm
Stretched exponential decay:
τ=1.3 ns, β=0.50
Ref: T. Uchino, N. Kurumoto, and N. Sagawa, PRB 73, 233203 (2006); A. Aboshi, N, Kurumoto, T. Yamada, and T. Uchino, JPCC 111, 8483 (2007)

シリカベース有機無機複合発光体


Emission quantum yield: ca 20 %
PL: 400-450 nm
PLE: 350 nm
Triple exponential decay:
decay constants: 4, 20, 70 ns
Ref: A. Nishimura, N. Sagawa, and Uchino, JPCC 113, 4260 (2009)

Si微粒子(prepared by an electron beam evaporation method with SiO and SiO2 particles)


Emission quantum yield: ca 1 %
PL: 730-760 nm
PLE: below 370 nm
Stretched exponential decay:
τ=10-50 μs, β=0.52-0.56
Ref: E. Koyanagi and T. Uchino, APL 91, 041910 (2007); D. Gautam, E. Koyabnagi, and T. Uchino, JAP 105, 073517 (2009)

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