Osakai Lab. Recent Publications

Recent Publications

別刷またはPDFの送付をご希望の方は大堺までご請求下さい。
Kernel は神戸大学の機関リポジトリーです。Kernel の表示がある論文は全文(最終原稿)にリンクできます。

If you would like to have any reprint(s) or pdf file(s), please feel free to contact T. Osakai, Ph.D.
Kernel is the institutional repository of Kobe University. For a paper labeled with "Kernel", you can link to the full-text (final manuscript).

(To be published)

先端の分析法 新訂第2版(仮題)
澤田嗣郎監修,エヌ・ティー・エス,刊行予定
(分担執筆:大堺担当:2-6-1項 膜電位と液間電位,2-6-2項 ポテンシオメトリー)


 (2021)

new A Theoretical Approach to the Fluorophilicity of Ions via the Gibbs Energy of Ion Transfer at the Fluorous Solvent/Water Interface
T. Osakai* , T. Kato, K. Eda, K. Uematsu, and H. Katano
Anal. Sci., published online.

new Fluorination Effect on the Gibbs Transfer Energy for Methylene Group from 1,2-Dichloroethane or 1,1,1,2,3,4,4,5,5,5-Decafluoropentane to Water
K. Uematsu*, J. Yamagata, H. Sakae, H. Katano, and T. Osakai
Anal. Sci., published online.

newIon-Transfer Voltammetry at Fluorous Ether | Water Interfaces
K. Uematsu*, Y. Matsubara, H. Katano, and T. Osakai

Anal. Sci., published online.

化学便覧 基礎編 改訂6版
日本化学会編,丸善,2021年1月刊行
(分担執筆:大堺担当:5章 電気化学,5.2節 電解質)


(2020)

ボルタンメトリーによる黄銅を含む銅材料の腐食生成物の成長機構の解析
中山茂吉*,富永愛子,藤岡寛之,能登谷武紀,大堺利行
材料と環境,69, 10-16 (2020).
[Analysis on the Growth Mechanism of Corrosion Products of Copper Materials Containing Brass by Voltammetry, S. Nakayama*, A. Tominaga, H. Fujioka, T. Notoya, and T. Osakai, Zairyo-to-Kankyo, 69, 10-16 (2020), in Japanese with English abstract and figures]


(2019)

Conversion Reaction of Polyoxometalates from Anderson Structure to Keggin Structure
T. Yamakawa*, K. Eda*, T. Osakai, and T. Nakajima
J. Comput. Chem. Jpn., 18, 257-258 (2019)

Computational Prediction of Adsorption Equilibrium for Nonionic Surfactants at the Oil/Water Interface
N. Somekawa, A Yamauchi, K. Eda, and T. Osakai*
Langmuir, 35, 11345-11350 (2019)

Gibbs Transfer Energies of Ions from a Mixed Solvent of 2H,3H-Decafluoropentane and 1,2-Dichloroethane to Water
H. Katano*, K. Uematsu, Y. Kuroda, and T. Osakai
Anal. Sci., 35, 1031-1035 (2019).
Selected as a "Hot Article" and appearing on the cover of the journal:

Is the Oil|Water Interface the Simplest and Best Suited Model for Understanding Biomembranes? (review)
T. Osakai*
Anal. Sci., 35, 361-366 (2019).

Directional Electron Transfer from Ubiquinone-10 to Cytochrome c at a Biomimetic Self-Assembled Monolayer Modified Electrode
T. Osakai*, T. Yamamoto, and M. Ueki
Electrochemistry, 87, 59-64 (2019)


(2018)

A Strategy for in Silico Prediction of the Membrane Permeability of Drugs
Y. Fujii, E. Yoshida, and T. Osakai*
Bull. Chem. Soc. Jpn., 91, 1618-1624 (2018).
Selected as a "Selected Paper" Kernel

Prediction of the Standard Gibbs Energy of Ion Transfer across the 1,2-Dichloroethane/Water Interface
A. Yamada, E. Yoshida, K. Eda, and T. Osakai*
Anal. Sci., 34, 919-924 (2018).

(巻頭言)質量作用の法則
大堺利行
Rev. Polarogr., 64, 1-2 (2018).
[Law of Mass Action (preface), T. Osakai, Rev. Polarogr., 64, No.1, 1-2 (2018), in Japanese
]

Solvate and Protic Ionic Liquids from Aza-crown Ethers: Synthesis, Thermal Properties, and LCST Behavior
Y. Oba, M. Okuhata, T. Osakai, and T. Mochida*

Phys. Chem. Chem. Phys., 20, 3118-3127 (2018).


(2017)

Can Electron-rich Oxygen (O2-) Withdraw Electrons from Metal Centers? ―A DFT Study on Oxoanion-caged Polyoxometalates
A. Takazaki*, K. Eda*, T. Osakai, and T. Nakajima
J. Phys. Chem. A, 121, 7684-7689 (2017).

Quantum Chemical Study on the Multi-electron Transfer of Keggin-type Polyoxotungstate Anions: the Relation of Redox Potentials to the Bond Valence of μ4-O−W (Letter)
A. Takazaki*, K. Eda*, T. Osakai, and T. Nakajima
J. Comput. Chem. Jpn., 16, 93-95 (2017).

編集後記 (Editor's Note;潮時)
大堺利行
Rev. Polarogr., 63, No. 2, 132 (2017).

電気分析化学、ここがむずかしい! (Part 1)(解説)
山本雅博 編,Rev. Polarogr., 63, No. 2, 119-125 (2017).
(大堺担当:酸化体か還元体しかないとき,平衡電極電位は±∞ボルト ?,p. 120)

[That's the Thing in Electroanalytical Chemistry! (Part 1) (explanatory), ed by M. Yamamoto, Rev. Polarogr., 63, No. 2, 119-125 (2017); T. Osakai was in charge of the subject "In the Presence of Only the Oxidized or Reduced Form of a Redox Species, Does the Equilibrium Electrode Potential Become ±∞ Volt ?", p. 120, in Japanese]

(講座)カールフィッシャー滴定による水分量測定の原理
大堺利行
Rev. Polarogr., 63, No. 2, 101-107 (2017).
[The Principle of Water-Content Determination by Karl Fischer Titration (tutorial), T. Osakai, Rev. Polarogr., 63, No. 2, 101-107 (2017), in Japanese with English abstract]

Determination of the Electrostatic Potential of Oil-in-Water Emulsion Droplets by Combined Use of Two Membrane Potential-Sensitive Dyes
T. Iwata, H. Nagatani, and T. Osakai*
Anal. Sci., 33, 813-819 (2017).
Selected as a "Hot Article" and appearing on the cover of the journal:

加熱した錫めっき純銅板および黄銅板における錫めっき層の状態分析(技術論文)
中山茂吉*,藤岡寛之,能登谷武紀,大堺利行
表面技術,68, 349-354 (2017).
[Chemical State Analysis of Heat-Treated Tin Plating on Pure Copper and Brass (Techlonogical Reports), S. Nakayama*, H. Fujioka, T. Notoya, and T. Osakai, J. Surf. Finish. Soc. Jpn., 68, 349-354 (2017), in Japanese with English abstract and figures]

Ion Transfer at the Interface between Water and Fluorous Solvent 1,1,1,2,3,4,4,5,5,5-Decafluoropentane
H. Katano*, K. Uematsu, Y. Kuroda, and T. Osakai

J. Electroanal. Chem., 796, 82-87 (2017).


(2016)

hakaru_hyakka自然科学のための はかる百科new
渥美茂明,尾関 徹,越桐國雄,関 隆晴,西村年晴,松村京子,横井邦彦 編,丸善,2016年11月 (ISBN978-4-621-30048-0)
(大堺担当:第 II 部,2.12節,化学反応をはかる)

(講座)ラプラス変換の電気化学への応用
大堺利行
Rev. Polarogr., 62, 109-114 (2016). Errata
[Application of Laplace Transform to Electrochemistry (tutorial), T. Osakai, Rev. Polarogr., 62, No. 2/3, 109-114 (2016), in Japanese with English abstract
]

Evaluation of the Membrane Permeability of Drugs by Ion-Transfer Voltammetry with the Oil|Water Interface
M. Nakamura and T. Osakai*

J. Electroanal. Chem., 779, 55-60 (2016) (Special issue in honor of Koichi Aoki).

Photoinduced Charge-Transfer State of 4-Carbazolyl-3-(trifluoromethyl)benzoic Acid: Photophysical Property and Application to Reduction of Carbon−Halogen Bonds as a Sensitizer
R. Matsubara*, T. Shimada, Y. Kobori*, T. Yabuta, T. Osakai, and M. Hayashi
Chem. Asian J., 11, 2006-2010 (2016).

強アルカリ性電解液を用いる銅腐食生成物の高選択的な電気化学分析
中山茂吉*,能登谷武紀,大堺利行
銅と銅合金, 55, 300-304 (2016).
[Highly Selective Electrochemical Analysis of Copper Corrosion Products Using the Strongly Alkaline Electrolyte, S. Nakayama*, T. Notoya, and T. Osakai, J. JRICu, 55, 300-304 (2016), in Japanese with English abstract and figures]

Evaluation of the Artificial Membrane Permeability of Drugs by Digital Simulation
M. Nakamura and T. Osakai*
Eur. J. Pharm. Sci., 91, 154-161 (2016).

編集後記 (Editor's Note;千田 貢先生)
大堺利行
Rev. Polarogr., 62, No. 1, 52 (2016).

(特集)蛍光色素diOC2(3)が吸着した油水界面へのアルカリ金属・アルカリ土類金属イオンの促進移動
森口弥香,永谷広久,枝 和男,大堺利行*
分析化学, 65, No. 2, 71-77 (2016).
[Facilitated Transfer of Alkali and Alkaline-Earth metal Ions to the Oil|Water Interface Where the Fluorescent Dye diOC2(3) is Adsorbed, M. Moriguchi, H. Nagatani, K. Eda, and T. Osakai*, Bunseki Kagaku, 65, No. 2 (special issue), 71-77 (2016), in Japanese with English abstract, table, and figures]

「新規な分離・検出の場としての溶液界面」特集号の刊行にあたって
特集小委員長 大堺利行
分析化学, 65, No. 2, 55; No. 3, 111 (2016).


(2015)

日本分析化学会学会賞受賞
大堺利行
くさだより,No. 26, p. 19 (2015).

ボルタンメトリーによる緑青を含む腐食生成物の化学状態分析
中山茂吉*,能登谷武紀,大堺利行
材料と環境, 64, 508-513 (2015).

[Chemical State Analysis of Copper Corrosion Products Including Patina by Voltammetry, S. Nakayama*, T. Notoya, and T. Osakai, Zairyo-to-Kankyo, 64, 508-513 (2015), in Japanese with English abstract, table, and figures
]

編集後記 (Editor's Note;玉虫伶太先生)
大堺利行
Rev. Polarogr., 61, No. 3, 306 (2015).

Prediction of the Standard Gibbs Energy of Transfer of Organic Ions across the Interface between Two Immiscible Liquids
T. Osakai*, Y. Naito, K. Eda, and M.
Yamamoto
J. Phys. Chem. B, 119, 13167-13176 (2015).

(総説)ヘテロポリ酸イオンの多電子移動反応メカニズム
枝 和男*,大堺利行
Rev. Polarogr., 61, No. 2, 77-86 (2015).
[Mechanisms of Multi-Electron Transfer Reactions for Heteropolyanions (review), K. Eda* and T. Osakai, Rev. Polarogr., 61, No. 2, 77-86 (2015), in Japanese with English abstract
]

The Effect of Supporting Electrolyte on the Electron Transfer at Mixed Self-Assembled Monolayers Containing Ferrocene Moieties
K. Shiota and T. Osakai*

J. Electroanal. Chem., 754, 75-79 (2015).

編集後記 (Editor's Note;角谷忠昭先生)
大堺利行
Rev. Polarogr., 61, No. 1, 53 (2015).

Coextraction of Water into Nitrobenzene with Organic Ions
Y. Naito, W. Murakami, K. Eda, M. Yamamoto, and T. Osakai*

J. Phys. Chem. B, 119, 6010-6017 (2015).

A Role of the Membrane|Solution Interface in Electron Transfer at Self-Assembled Monolayer Modified Electrodes
K. Shiota, M. Ueki, and T. Osakai*
J. Electroanal. Chem., 745, 22-27 (2015).

基礎分析化学
小熊幸一,酒井忠雄 編,朝倉書店, 2015年3月 (ISBN978-4-254-14102-3)

(大堺担当:8章,電気化学分析)

How Can Multi-Electron Transfer Be Realized? A Case Study with Keggin-Type Polyoxometalates in Acetonitrile
K. Eda* and T. Osakai
Inorg. Chem., 54, 2793-2801 (2015)
.


(2014)

編集後記 (Editor's Note;60巻の還暦)
大堺利行
Rev. Polarogr., 60, No. 3, 290 (2014).

A Non-Bornian Analysis of the Gibbs Energy of Hydration for Organic Ions
W. Murakami, M. Yamamoto, K. Eda, and T. Osakai*
RSC Adv., 4, 27634-27641 (2014).

編集後記 (Editor's Note;“STAP細胞”)
大堺利行
Rev. Polarogr., 60, No. 1, 76 (2014).

Combined Use of Two Membrane-Potential-Sensitive Dyes for Determination of the Galvani Potential Difference across a Biomimetic Oil/Water Interface
T. Yoshimura, H. Nagatani, and T. Osakai*
Anal. Bioanal. Chem., 406, 3407-3414 (2014).

巻頭言
大堺利行
ぶんきんニュース, No. 31, 2 (2014).

(とびら)Mehr Zeit!
大堺利行
ぶんせき, No. 4, 143 (2014).

A Non-Bornian Analysis of the Gibbs Energy of Ion Hydration
W. Murakami, K. Eda, M. Yamamoto, and T. Osakai*
Bull. Chem. Soc. Jpn., 87, 403-411 (2014).


(2013)

編集後記 (Editor's Note;"Work, Finish, Publish")
大堺利行
Rev. Polarogr., 59, No. 3, 238 (2013).

榎本武揚と土方歳三 −明暗を分けたもの−
大堺利行
近畿化学工業界, No. 9, 5-6 (2013).

A Revisit to the Non-Bornian Theory of the Gibbs Energy of Ion Transfer between Two Immiscible Liquids
W. Murakami, K. Eda, M. Yamamoto, and T. Osakai*
J. Electroanal. Chem., 704, 38-43 (2013).

編集後記 (Editor's Note;Polarography)
大堺利行
Rev. Polarogr., 59, No. 1, 37 (2013).

Theoretical Similarity between Macro- and Nano-interfaces (Electrochemical Concepts)
T. Osakai
Rev. Polarogr., 59, 21-27 (2013).

Sophisticated Design of PVC Membrane Ion-Selective Electrodes Based on the Mixed Potential Theory
M. Imoto, T. Sakaki, and T. Osakai*
Anal. Chem., 85, 4753-4760 (2013).

Electrochemical Characterization of a Unique, "Neutral" Laccase from Flammulina velutipes
K. (Otsuka) Saito, S. Kurose, Y. Tsujino*, T. Osakai, K. Kataoka, T. Sakurai, and E. Tamiya
J. Biosci. Bioeng., 115, 159-167 (2013).

第6版 電気化学便覧
電気化学会編,丸善,2013年1月 (ISBN 978-4-621-08413-7)
(大堺担当:4.3節,電気化学平衡/5.2節,サイクリックボルタンメトリー,いずれも共著)

正誤表

アンモニア緩衝液を支持電解質に用いるボルタンメトリーによる錫酸化皮膜の化学状態分析
中山茂吉*,杉原崇康,能登谷武紀,大堺利行
材料と環境,62, 16-21 (2013).
[Chemical State Analysis of Tin Oxide Films by Voltammetry using Ammonia Buffer as the Supporting Electrolyte, S. Nakayama*, T. Sugihara, T. Notoya, and T. Osakai, Zairyo-to-Kankyo, 62, 16-21 (2013), in Japanese with English abstract and figures]


(2012)

Amperometric Determination of Creatinine with a Dialysis Membrane-covered Nitrobenzene/Water Interface for Urine Analysis
R. Matsui, T. Sakaki, and T. Osakai*
Electroanalysis, 24, 2325-2331 (2012).

"Electrochemical Dictionary, 2nd Edition," ed by A. J. Bard, G. Inzelt, and F. Scholz, Springer, Berlin (2012) (ISBN 978-3-642-29551-5)
(T. Osakai contributed 25 entries including "anode", "cathode", "column electrode", "electrocapillary curve", "electroinactive species", "ECSOW system", "exchange current density", "four-electrode system", "Grotthuss mechanism", "Hofmeister series", "hydrated ion", "ion", "ion association", "ion-dipole interaction", "ion exchange", "ion-exchange membrane", "ionic potential", "ionic mobility", "Luggin capillary", "molar ionic conductivity", "oil-water interface", "positive feedback circuit", "residual current", "Masuzo Shikata", and "transition time")

Book Review by Prof. D. Mandler Here

(書評)電気化学分析(木原壯林,加納健司 著)
大堺利行
Electrochemistry, 80, 843 (2012).

Potential-Modulated Fluorescence Spectroscopy of Zwitterionic and Dicationic Membrane-Potential-Sensitive Dyes at the 1,2-Dichloroethane/Water Interface
T. Osakai*, T. Yoshimura, D. Kaneko, H. Nagatani, S.-H. Son, Y. Yamagishi, and K. Yamada
Anal. Bioanal. Chem., 404, 785-792 (2012).

Application of the Mixed-Potential Theory to the Interpretation of the Potential Response of a PVC Membrane Ion-Selective Electrode for Desipramine
T. Osakai*, M. Imoto, Y. Sato, and T. Sakaki
Anal. Sci., 28, 565-570 (2012).

Label-Free Amperometric Detection of Albumin with an Oil/Water-type Flow Cell for Urine Protein Analysis
R. Matsui, T. Sakaki, and T. Osakai*
Electroanalysis, 24, 1164-1169 (2012).

Highly Selective Determination of Copper Corrosion Products by Voltammetric Reduction in a Strongly Alkaline Electrolyte (review)
S. Nakayama*, T. Notoya, and T. Osakai*

Anal. Sci., 28, 323-331 (2012).
daibutsu&megami

Interpretation of the Potential Response of PVC Membrane Ion-Selective Electrodes Based on the Mixed Potential Theory
T. Osakai*, Y. Sato, M. Imoto, and T. Sakaki
J. Electroanal. Chem., 668, 107-112 (2012).

Electron Transfer Mechanism of Cytochrome c at the Oil/Water Interface as a Biomembrane Model
Y. Imai, T. Sugihara, and T. Osakai*
J. Phys. Chem. B, 116, 585-592 (2012).


(2011)

腐食防食協会論文賞受賞
大堺利行
くさだより,No. 22, p. 22 (2011).

Cathodic Reduction of Copper Oxides (review)
Y.-Y. Su*, S. Nakayama, and T. Osakai
Corros. Rev., 29.
51-71 (2011).

Chemical State Analysis of Tin Oxide Films by Voltammetric Reduction
S. Nakayama*, T. Sugihara, J. Matsumoto, T. Notoya, and T. Osakai*
J. Electrochem. Soc., 158, C341-C345 (2011).

Electron Transfer Mediated by Membrane-bound D-Fructose Dehydrogenase Adsorbed at an Oil/Water Interface
Y. Sasaki, T. Sugihara, and T. Osakai*
Anal. Biochem., 417, 129-135 (2011).


(2010)

高アルカリ電解液を用いる銅腐食生成物のボルタンメトリー定量における留意点
中山茂吉*,能登谷武紀,大堺利行
銅と銅合金, 49, 273-277 (2010).
[Instructions for Voltammetric Determination of Copper Corrosion Products Using a Strongly Alkaline Electrolyte, S. Nakayama*, T. Notoya, and T. Osakai, J. JRICu, 49, 273-277 (2010), in Japanese with English abstract and figures]

A Mechanism for the Atmospheric Corrosion of Copper Determined by Voltammetry with a Strongly Alkaline Electrolyte
S. Nakayama*, T. Notoya, and T. Osakai*
J. Electrochem. Soc., 157, C289-C294 (2010).

Direct Label-free Electrochemical Detection of Proteins Using the Polarized Oil/Water Interface
T. Osakai
*, Y. Yuguchi, E. Gohara, and H. Katano
Langmuir, 26, 11530-11537 (2010).

Flow-Injection On-line Electrochemical Separation/Determination of Ions Using a Two-Step Oil/Water-Type Flow Cell System
E. Gohara and T. Osakai*
Anal. Sci., 26, 375-378 (2010).


(2009)

(使える解析テクニック! 具体例で説明する電気化学測定法) 分極曲線・サイクリックボルタンメトリー(8)液液界面
大堺利行
Electrochemistry, 77 (10), 899-903 (2009).

Potential-Modulated Fluorescence Spectroscopy of the Membrane Potential-Sensitive Dye Di-4-ANEPPS at the 1,2-Dichloroethane/Water Interface
T. Osakai*, J. Sawada, and H. Nagatani
Anal. Bioanal. Chem., 395, 1055-1061 (2009).

Bimolecular-Reaction Effect on the Rate Constant of Electron Transfer at the Oil/Water Interface as Studied by Scanning Electrochemical Microscopy
T. Osakai*, M. Okamoto, T. Sugihara, and K. Nakatani
J. Electroanal. Chem., 628, 27-34 (2009).
Kernel

Kinetic Analysis of Electron Transfer across Single Water-Microdroplet/Oil and Oil-Microdroplet/Water Interfaces
K. Nakatani*, M. Uchino, S. Suzuki, T. Negishi, and T. Osakai
Anal. Sci., 25, 183-187 (2009).


(2008)

編集後記 (Editor's Note)
大堺利行
Rev. Polarogr., 54, No. 2, 134 (2008).

(とびら)Analytical Sciences誌の更なる飛躍を期して
大堺利行
ぶんせき, No. 8, 379 (2008).

Correlation between Reduction Potentials and Inhibitions of Epstein-Barr Virus Activation by Anthraquinone Derivatives
J. Koyama*, Y. Nisino, I. Morita, N. Kobayashi, T. Osakai, and H. Tokuda
Bioorg. Med. Chem. Lett., 18, 4106-4109 (2008).

高アルカリ液を用いるボルタンメトリーによる銅硫化物の定量分析
中山茂吉*,楫登紀子,能登谷武紀,大堺利行
材料と環境, 57, 327-333 (2008). 平成23年度腐食防食協会「論文賞」受賞!
[Quantitative Analysis of Copper Sulfides by Voltammetry Using a Strongly Alkaline Solution, S. Nakayama*, T. Kaji, T. Notoya, and T. Osakai, Zairyo-to-Kankyo, 57, 327-333 (2008), in Japanese with English abstract, tables, and figures; the English translation is available in Corros. Eng. (ISSN 0892-4228), 57, 419-431 (2008)]

"Electrochemical Dictionary" ed by A. J. Bard, G. Inzelt, and F. Scholz, Springer, Berlin (2008) (ISBN 978-3-540-74597-6)
(T. Osakai contributed 25 entries including "anode", "cathode", "column electrode", "electrocapillary curve", "electroinactive species", "ECSOW system", "exchange current density", "four-electrode system", "Grotthuss mechanism", "Hofmeister series", "hydrated ion", "ion", "ion association", "ion-dipole interaction", "ion exchange", "ion-exchange membrane", "ionic potential", "ionic mobility", "Luggin capillary", "molar ionic conductivity", "oil-water interface", "positive feedback circuit", "residual current", "Masuzo Shikata", and "transition time")

Electrochemical Aspects of the Reverse Micelle Extraction of Proteins
T. Osakai* and A. Shinohara
Anal. Sci., 24, 901-906 (2008). Selected as a "Hot Article"

ベーシック機器分析化学
日本分析化学会近畿支部 編
化学同人,2008年7月  (ISBN 978-4-7598-1144-5)
(大堺担当:第III部 0章,電気化学反応の基礎/1章,ボルタンメトリー)

ベンゾトリアゾール −銅および銅合金の腐食抑制剤−
能登谷武紀,中山茂吉,大堺利行 共著
日本防錆技術協会,2008年6月

Correlation between Oxidation Potentials and Inhibitory Effects on Epstein-Barr Virus Activation of Flavonoids
J. Koyama*, I. Morita, N. Kobayashi, T. Konoshima, M. Takasaki, T. Osakai, and H. Tokuda
Cancer Lett., 263, 61-66 (2008).

(解説)銅酸化物の定量的な状態別分析法
中山茂吉,大堺利行,能登谷武紀
防錆管理52, 112-119 (2008).

Mechanistic Study of the Reduction of Copper Oxides in Alkaline Solutions by Electrochemical Impedance Spectroscopy
S. Nakayama*, T. Kaji, T. Notoya, and T. Osakai
Electrochim. Acta, 53, 3493-3499 (2008).

A Mechanistic Study of the Oxidation of Natural Antioxidants at the Oil/Water Interface Using Scanning Electrochemical Microscopy
T. Sugihara, T. Kinoshita, S. Aoyagi, Y. Tsujino, and T. Osakai*
J. Electroanal. Chem., 612, 241-246 (2008). Kernel


(2007)

Electrochemical Consideration on the Optimum pH of Bilirubin Oxidase
K. Otsuka, T. Sugihara, Y. Tsujino, T. Osakai, and E. Tamiya*
Anal. Biochem., 370, 98-106 (2007).

Cationic-Surfactant Transfer Facilitated by DNA Adsorbed on a Polarized 1,2-Dichloroethane/Water Interface
T. Osakai*, H. Komatsu, and M. Goto
J. Phys. Cond. Matt., 19, 375103 (11pp) (2007). Kernel

Potential-Dependent Adsorption of Amphoteric Rhodamine Dyes at the Oil/Water Interface as Studied by Potential-Modulated Fluorescence Spectroscopy
T. Osakai*, H. Yamada, H. Nagatani*, and T. Sagara
J. Phys. Chem. C, 111, 9480-9487 (2007).

(書評)分析化学(S. P. J. Higson著,阿部芳廣,渋川雅美,角田欣一 訳)
大堺利行
現代化学,No. 433, 70 (2007).

(話題)Analytical Sciences誌のインパクトファクターを考える
大堺利行
ぶんせき, No. 3, 143-144 (2007).
[On the Impact Factor of Analytical Sciences (review), T. Osakai, Bunseki, 143-144 (2007), in Japanese]

Which Is Easier to Reduce, Cu2O or CuO?
S. Nakayama, T. Kaji, M. Shibata, T. Notoya, and T. Osakai*
J. Electrochem. Soc., 154, C1-C6 (2007).


(2006)

電気化学測定のための基礎技術(2)(解説)
木原壯林 編,Rev. Polarogr., 52, 89-107 (2006).
(大堺担当:油水界面電荷移動ボルタンメトリー用の四電極式電解セルの作製,pp. 90-93.

[Fundamental Techniques for Electrochemical Measurements (Part 2)(review), ed by S. Kihara, Rev. Polarogr., 52, 89-107 (2006); T. Osakai was in charge of the subject "Fabrication of a Four-Electrode Electrolytic Cell for Charge-Transfer Voltammetry with the Oil/Water Interface", pp. 90-93, in Japanese]

Correlation between Reduction Potentials and Inhibitory Effects on Epstein-Barr Virus Activation by Emodin Derivatives
J. Koyama*, M. Inoue, I. Morita, N. Kobayashi, T. Osakai, H. Nishino, and H. Tokuda
Cancer Lett., 241, 263-267 (2006).

Electrochemical Extraction of Proteins by Reverse Micelle Formation
M. Shinshi, T. Sugihara, T. Osakai*, and M. Goto
Langmuir, 22, 5937-5944 (2006). [Corrections: ibid, 22, 8614 (2006)]

油水界面イオン移動の標準電位(総説)
大堺利行
Rev. Polarogr., 52, 3-12 (2006).
[Standard Potentials for the Transfer of Ions at the Oil/Water Interface (review), T. Osakai, Rev. Polarogr., 52, 3-12 (2006)]

Quantitative Analysis of the Structure-Hydrophobicity Relationship for Di- and Tripeptides Based on Voltammetric Measurements with an Oil/Water Interface
T. Osakai*, T. Hirai, T. Wakamiya, and S. Sawada
Phys. Chem. Chem. Phys., 8, 985-993 (2006). Kernel

Direct Spectroelectrochemical Observation of Interfacial Species at the Polarized Water/1,2-Dichloroethane Interface by Ac Potential Modulation Technique
H. Nagatani*, T. Ozeki, and T. Osakai
J. Electroanal. Chem., 588, 99-105 (2006).


(2005)

Correlation between Reduction Potentials and Inhibitory Effects on Epstein-Barr Virus Activation of Poly-substituted Anthraquinones
J. Koyama*, I. Morita, N. Kobayashi, T. Osakai, H. Nishino, and H. Tokuda
Cancer Lett., 225, 193-198 (2005).

油水界面の電気分析化学における最近の進歩(総説)
大堺利行*,片野 肇
分析化学,54, 251-266 (2005).
[Recent Developments in the Electroanalytical Chemistry at an Oil|Water Interface (review),T. Osakai* and H. Katano, Bunseki Kagaku, 54, 251-266 (2005), in Japanese]

(電気化学:測定と解析のてびき) サイクリックボルタンメトリー(2)準可逆波,非可逆波
大堺利行,加納健司
Electrochemistry, 73, 310-313 (2005).

(電気化学:測定と解析のてびき) サイクリックボルタンメトリー(1)可逆波
加納健司,大堺利行
Electrochemistry, 73, 220-224 (2005).

Structure-Activity Relationship of Azafluorenone and Azaanthraquinone as Antimicrobial Compounds
J. Koyama*, I. Morita, N. Kobayashi, T. Osakai, Y. Usuki, and M. Taniguchi
Bioorg. Med. Chem. Lett., 15, 1079-1082 (2005).

Electron Transfer at Liquid/Liquid Interfaces
T. Osakai and H. Hotta
In
"Interfacial Nanochemistry" ed by H. Watarai, N. Teramae, and T. Sawada, Kluwer/Plenum, New York, Chap. 8 (pp. 171-188) (2005).

Electron Transfer across the Single Micro-Water-Droplet|Oil Interface Using Microcapillary Injection and Microelectrode Methods
K. Nakatani*, J. Yamashita, T. Negishi, and T. Osakai
J. Electroanal. Chem., 575, 27-32 (2005).


(2004)

Photoinduced Electron Transfer of 5,10,15,20-Tetraphenylporphyrinato Zinc(II) at the Polarized Water/1,2-Dichloroethane Interface
H. Nagatani*, S. Dejima, H. Hotta, T. Ozeki, and T. Osakai*
Anal. Sci., 20, 1575-1579 (2004).

A True Electron-Transfer Reaction between 5,10,15,20-Tetraphenylporphyrinato Cadmium(II) and the Hexacyanoferrate Couple at the Nitrobenzene/Water Interface
T. Osakai*, S. Ichikawa , H. Hotta, and H. Nagatani
Anal. Sci., 20, 1567-1573 (2004).

Diffusion-controlled Rate Constant of Electron Transfer at the Oil/Water Interface
T. Osakai*, H. Hotta, T. Sugihara, and K. Nakatani
J. Electroanal. Chem., 571, 201-206 (2004). Kernel

銅酸化物及び水酸化物の粉末試料のボルタンメトリーによる化学状態分析
中山茂吉*,柴田雅裕,大堺利行,能登谷武紀
銅と銅合金43, 235-239 (2004).
[Voltammetric Chemical State Analysis of Copper Oxides and Hydrooxide in Powder Samples, S. Nakayama*, M. Shibata, T. Osakai, and T. Notoya, J. JRICu, 43, 235-239 (2004), in Japanese with English abstract and figures]

電気化学的還元法による緋色銅表面酸化物の決定
能登谷武紀*,中山茂吉,楫 登紀子,大堺利行
銅と銅合金43, 232-234 (2004).
[Identification of Reddish-brown Copper Oxide on Copper by the Electrochemical Reduction Method, T. Notoya*, S. Nakayama, T. Kaji, and T. Osakai, J. JRICu, 43, 232-234 (2004), in Japanese with English abstract and figures]

Product Analysis of Caffeic Acid Oxidation by On-line Electrochemistry/Electrospray Ionization Mass Spectrometry
R. Arakawa*, M. Yamaguchi, H. Hotta, T. Osakai, and T. Kimoto
J. Am. Soc. Mass Spectrom., 15, 1228-1236 (2004).

Correlation of Redox Potentials and Inhibitory Effects on Epstein-Barr Virus Activation of 2-Azaanthraquinones
J. Koyama*, I. Morita, N. Kobayashi, T. Osakai, H. Hotta, J. Takayasu, H. Nishino, and H. Tokuda
Cancer Lett., 212, 1-6 (2004).

Electrochemical Control of Glucose Oxidase Catalyzed Redox Reaction Using an Oil/Water Interface
T. Sugihara, H. Hotta, and T. Osakai*
Phys. Chem. Chem. Phys., 6, 3563-3568 (2004). Kernel

オンライン電解/エレクトロスプレーイオン化質量分析法によるカテキン類の酸化過程の研究
山口正史,溝奥康夫,大堺利行,紀本岳志,荒川隆一*
分析化学, 53, 547-553 (2004).
[Study of the Oxidation Processes of Catechins by On-line Electrolysis/ESI-MS, M. Yamaguchi, Y. Mizooku T. Osakai, T. Kimoto, and R. Arakawa*, Bunseki Kagaku, 53, 547-553 (2004), in Japanese with English abstrac, tables, and figures]

化学便覧 基礎編,改訂5版
日本化学会編,
丸善,2004年2月
(大堺担当:13.1.4項,油水界面イオン移動の標準ギブズエネルギーと標準イオン移動電位,pp. II-578-II-579)


(2003)

(特集)油水界面電子移動の反応機構解明への新しいアプローチ
大堺利行,堀田弘樹
ぶんせき, No. 12, 746-748 (2003).

Correlation with Redox Potentials and Inhibitory Effects on Epstein-Barr Virus Activation of Naphthoquinones
J. Koyama*, I. Morita, N. Kobayashi, T. Osakai, H. Hotta, J. Takayasu, H. Nishino, and H. Tokuda
Cancer Lett., 201, 25-30 (2003).

銅表面に生成した酸化第一銅及び酸化第二銅の分析法に関する研究(技術論文)
中山茂吉,柴田雅裕,能登谷武紀,大堺利行
SEIテクニカルレビュー, No. 163, 39-42 (2003).
[The English edition: Voltammetric Determination of Cupric and Cuprous Oxides Formed on Copper, S. Nakayama, M. Shibata, T. Notoya, and T. Osakai, SEI Tech. Rev., No. 57, 22-25 (2004), in Japanese with English abstract]

Temperature Effect on the Selective Hydration of Sodium Ion in Nitrobenzene
T. Osakai*, A. Tokura, H. Ogawa, H. Hotta, M. Kawakami, and K. Akasaka
Anal. Sci., 19, 1375-1380 (2003).

Determination of the Entropy of Ion Transfer between Two Immiscible Liquids Using the Water|Oil|Water Thermocouple
T. Osakai*, H. Ogawa, T. Ozeki, and H.H. Girault
J. Phys. Chem. B, 107, 9829-9836 (2003).

Clarification of the Mechanism of the Interfacial Electron-Transfer Reaction between Ferrocene and Hexacyanoferrate(III) by Digital Simulation of Cyclic Voltammograms
H. Hotta, S. Ichikawa, T. Sugihara, and T. Osakai*
J. Phys. Chem. B, 107, 9717-9725 (2003).

サイクリックボルタモグラムのデジタルシミュレーションによるアスコルビン酸の油水界面電子移動の反応機構
杉原崇康,堀田弘樹,大堺利行*
分析化学, 52, 665-671 (2003).
[Mechanistic Study of the Electron Transfer of L-Ascorbic Acid at an Oil/Water Interface by a Digital Simulation of Cyclic Voltammograms, T. Sugihara, H. Hotta, and T. Osakai*, Bunseki Kagaku, 52, 665-671 (2003), in Japanese with English abstrac, table, and figures]

油水界面電子移動の反応機構に関する研究(総説)
堀田弘樹,大堺利行*
Rev. Polarogr., 49, 15-30 (2003).

[Mechanistic Study of Electron Transfer at the Oil/Water Interface (review), H. Hotta and T. Osakai*, Rev. Polarogr., 49, 15-30 (2003), in Japanese with English abstract, table, and figures]


(2002)

銅の空気酸化被膜の成長に関するボルタンメトリー的解析
中山茂吉*,柴田雅裕,桑畑 進,大堺利行,能登谷武紀
材料と環境, 51, 566-570 (2002).
[Voltammetric Characterization for the Growth of Oxide Films Formed on Copper in Air, S. Nakayama*, M. Shibata, S. Kuwabata, T. Osakai, and T. Notoya, Zairyo-to-Kankyo, 51, 566-570 (2002), in Japanese with English abstract, table, and figures; the English translation is available in Corros. Eng. (ISSN 0892-4228), 51, 787-796 (2002)]

The Role of Water Molecules in Ion Transfer at the Oil/Water Interface
T. Osakai
In
"Interfacial Catalysis" ed by A.G. Volkov, Marcel Dekker , Chap. 4 (pp. 53-82) (2002).

銅表面に生成した酸化第一銅及び酸化第二銅のボルタンメトリー測定の標準化に関する研究
中山茂吉*,柴田雅裕,能登谷武紀,大堺利行
分析化学,51, 1145-1152 (2002).
[On Standardizing to Voltammetric Determination of Cupric and Cuprous Oxides Formed on Copper, S. Nakayama*, M. Shibata, T. Notoya, and T. Osakai, Bunseki Kagaku, 51, 1145-1152 (2002), in Japanese with English abstract, table, and figures]

Higher Radical Scavenging Activities of Polyphenolic Antioxidants Can Be Ascribed to Chemical Reactions Following Their Oxidation
H. Hotta, S. Nagano, M. Ueda, Y. Tsujino, J. Koyama, and T. Osakai*
Biochim. Biophys. Acta, 1572, 123-132 (2002).

(トピックス) ワインの抗酸化力を電気化学ではかる
堀田弘樹
ぶんせき, No. 8, 458 (2002).

(測定法Q&A) 電極間の内部電位プロファイル
加納健司,大堺利行,桑畑 進
Electrochemistry, 70, 358-361 (2002), in Japanese with English figures.

イオン移動ボルタンメトリー用四電極式測定システムの性能評価
青柳重夫,松平昌昭,鈴木貴博,片野 肇,澤田惠夫,堀田弘樹,市川聖子,杉原崇康,大堺利行*
Electrochemistry, 70, 329-333 (2002).
[Performance Evaluation of the Four-Electrode Type Measurement System for Ion-Transfer Voltammetry, S. Aoyagi, M. Matsudaira, T. Suzuki, H. Katano, S. Sawada, H. Hotta, S. Ichikawa, T. Sugihara, and T. Osakai*, Electrochemistry, 70, 329-333 (2002), in Japanese with English abstrac, table, and figures]

Electron-Conductor Separating Oil-Water (ECSOW) System: a New Strategy for Characterizing Electron-Transfer Processes at the Oil/Water Interface
H. Hotta, N. Akagi, T. Sugihara, S. Ichikawa, and T. Osakai*
Electrochem. Commun., 4, 472-477 (2002).

Mechanistic Study of the Oxidation of Caffeic Acid by Digital Simulation of Cyclic Voltammograms
H. Hotta, M. Ueda, S. Nagano, Y. Tsujino, J. Koyama, and T. Osakai*
Anal. Biochem., 303, 66-72 (2002).

はかってなんぼ −学校編−
日本分析化学会近畿支部 編,丸善,2002年3月(ISBN 4-621-04996-8)
(大堺担当:3.4節,ばける,pp. 61-70/4.6節,リン,pp. 148-153)

(こんにちは)京都大学大学院農学研究科池田研究室を訪ねて
大堺利行
ぶんせき, 135-137 (2002).

Complete Electrolysis Using a Microflow Cell with an Oil/Water Interface
S. Sawada, M. Taguma, T. Kimoto, H. Hotta, and T. Osakai*
Anal. Chem., 74, 1177-1181 (2002).


(2001)

Voltammetric Characterization of Oxide Films Formed on Copper in Air
S. Nakayama*, A. Kimura, M. Shibata, S. Kuwabata, and T. Osakai
J. Electrochem. Soc., 148, B467-B472 (2001).

Correlation with Redox Potentials and Inhibitory Effects on Epstein-Barr Virus Activation of Azaanthraquinones
J. Koyama*, I. Morita, K. Tagahara, T. Osakai, H. Hotta, M.X. Yang, T. Mukainaka, H. Nishino, and H. Tokuda
Chem. Pharm. Bull., 49, 1214-1216 (2001).

Mechanistic Aspects Associated with the Oxidation of L-Ascorbic Acid at the 1,2-Dichloroethane|Water Interface
T. Osakai*, H. Jensen, H. Nagatani, D.J. Fermin, and H.H. Girault
J. Electroanal. Chem., 510, 43-49 (2001).

Selective Hydration of a Carboxylate Group in Nitrobenzene
T. Osakai*, S. Nakata, and H. Ogawa
Chem. Lett., 558-559 (2001).

Ion Transfer of Heteropolytungstate Anions at the Nitrobenzene|Water Interface and its Relevance to Their Antiviral Activities
J. Ding, H. Hotta, and T. Osakai*
J. Electroanal. Chem., 505, 133-141 (2001).

Unusually Large Numbers of Electrons for the Oxidation of Polyphenolic Antioxidants
H. Hotta, H. Sakamoto, S. Nagano, T. Osakai*, and Y. Tsujino
Biochim. Biophys. Acta, 1526, 159-167 (2001).

Ion Transfer of Reduced Keggin-type Heteropolymolybdate Anions at the Nitrobenzene/Water Interface and its Relevance to their Antitumoral Activities
J. Ding and T. Osakai*
Electroanalysis, 13, 384-391 (2001).

Ion Transfer and Photoinduced Electron Transfer of Water-soluble Porphyrin at the Nitrobenzene|Water Interface
T. Osakai* and K. Muto
J. Electroanal. Chem., 496, 95-102 (2001).

Ion Solvation and Resolvation
T. Osakai and K. Ebina
In "Liquid Interfaces in Chemical, Biological, and Pharmaceutical Applications" ed by A. G. Volkov, Marcel Dekker, Chap. 2 (pp. 23-49) (2001).

Book Review by Prof. D. Schiffrin: here


(2000)

Proton NMR Study on Selective Hydration of Anions in Nitrobenzene
T. Osakai*, M. Hoshino, M. Izumi, M. Kawakami, and K. Akasaka
J. Phys. Chem. B, 104, 12021-12027 (2000).

Mechanistic Study of the Oxidation of L-Ascorbic Acid by Chloranil at the Nitrobenzene|Water Interface
T. Osakai*, N. Akagi, H. Hotta, J. Ding, and S. Sawada
J. Electroanal. Chem., 490, 85-92 (2000).

ベーシック電気化学
大堺利行,加納健司,桑畑 進 共著
化学同人,平成12年9月ISBN 4-7598-0861-2
["Basic Electrochemisry" (textbook), T. Osakai, K. Kano, and S. Kuwabata, Kagaku Dojin (2000)]

Amazon.co.jp の書評は ここ

hontoネットストア の書評は ここ 

(談話室)美しい電気化学
大堺利行
Rev. Polarogr., 46, 8 (2000).
[Beautiful Electrochemistry (essay), T. Osakai, Rev. Polarogr., 46, 8 (2000), in Japanese]

はかってなんぼ −分析化学入門−
河合 潤,樋上照男 編,丸善,平成12年2月 (ISBN 4-621-04707-8)
(大堺担当:第7章,イオンセンサー〜錬金術から科学技術へ〜,pp. 73-81)

Selective Hydration of Alkylammonium Ions in Nitrobenzene
A. Ogata, Y. Tsujino, and T. Osakai*
Phys. Chem. Chem. Phys., 2, 247-251 (2000).


(1999-1981)

Here


To the Osakai Laboratory Homepage
To Toshiyuki OSAKAI's Profile (in English)